Wednesday 13 June 2012

Periodisasi Sastra Indonesia


Ciri-ciri ...

1. Angkatan ’20
   - bertema kawin paksa (menonjolkan adat)
   - masih terpengaruh Bahasa Melayu
   - roman yang pertama terbit, “Azab dan Sengsara” karya Merari Siregan
   - roman yang terkenal berjudul “Siti Nurbaya” karya Marah Rusli
   - angkatan ’20 disebut juga Angkatan Siti Nurbaya
   - 3 pengarang penting:  - Merari Siregar
                                         - Marah Rusli
                                         - Sutan Iskandar
2. Angkatan ’30
   - karya sastra bertema lebih luas, misalnya emansipasi wanita, moral manusia, dsb.
   - roman yang terkenal adalah “Layar Terkembang” karya Sutan Takdir Alisjahbana
   - roman yang sempat dilarang terbit berjudul “Belenggu” karya Armin Pane
   - 3 pengarang penting:  - Sutan Takdir Alisjahbana
                                         - Armin Pane
                                         - Amir Hamzah
3. Angkatan ‘45
   - puisi berteme revolusi kemerdekaan
   - tokoh puisi: Chairil Anwar (puisi terkenalnya berjudul “Aku”)
   - tokoh prosa: Idrus
   - karya-karya sastra lainnya disemangati oleh perjuangan kemerdekaan
   - 3 pengarang penting:  - Chairil Anwar
                                         - Achdiat Kartamiharja
                                         - Idrus

Tuesday 12 June 2012

Hydrocarbons Quiz


1. Write down the IUPAC name of the following alkane and show the main chain and the ordering number!
     CH3 – CH – CH – CH2 – CH2 – CH2
                |      |
              CH3   CH2
                        |
                       CH3

2. Write down the IUPAC name of the following alkene and show the main chain and the ordering number!
     CH3 – C = C – CH3
              |    |
             CH3 C2H5

3. Write down the IUPAC name of the following alkyne and show the main chain and the ordering number!
     CH3 – CH2 – C C – CH – CH2 – CH3
                                            |
                                          CH3

4. Write down the structural formula of the following hydrocarbon compound:
     3-ethyl-2,4-dimethylheptane

5. Which of the following isomers are chain isomers and position isomers?
     a. CH3 – CH2 – CH2 – CH2 – CH2 – CH2 – CH3

     b.          CH3
                    |
           CH3 – C – CH2 – CH2 – CH3
                    |
                   CH3

     c. CH3 – CH – CH2 – CH – CH
                    |               |
                   CH3          CH3
     Chain isomer: ...
      Position isomer: ...

6. Which of the following isomers have geometric isomerism?
     a. CH2 = CH – CH2 – CH3
     b. CH3 – CH = CH – CH2 – CH3

7. Complete the following hydrocarbon reactions:
     a.         H
                 |
           H – C – H   +   I2
                 |
                 H

     b.   H    H
            |    |
            C = C   +   Br2
            |    |
            H   H



Solutions:
1.  CH3 – CH – CH – CH2 – CH2 – CH2
                |      |
              CH3   CH2
                        |
                       CH3
naming starts from the left (1-2-3-4-5-6 :: hexane)
you have 2-methyl, and 3-ethyl
∴ 3-ethyl-2-methylhexane (e comes before m)

2.     CH3 – C = C – CH3
                 |     |
                CH3 CH2
                        |
                       CH3
break down C2H5 into CH2 and CH3
naming starts from the left CH3 - C = C, then down to CH2 - CH3 to make it the longest chain (2-pentene). *2 -> double bond   *ene -> alkene
you have 2-methyl and 3-methyl which becomes 2,3-dimethyl.
∴ 2,3-dimethyl-2-pentene.

3. CH3 – CH2 – C  C – CH – CH2 – CH3
                                           |
                                         CH3
naming starts from the left
∴ 5-methyl-3-heptyne

4. CH3 – CH – CH – CH – CH2 – CH2 – CH3
               |     |      |
            CH3  CH2 CH3
                      |
                     CH3
(naming starts from the left)
For those of you who are still confused on how to write the chains, I start by writing a line of C's as long as main chain is (in this case, heptane = 7). Then I add the branches: ethyl to number 3, and methyl to numbers 2 and 4.

5. Chain isomer: a and b, a and c
     Position isomer: b and c

6. b

7. a.              H
                     |
           H – I – C – I – H
                     |
                     H

   b.          H   H
                 |   |
          Br – C – C – Br
                 |   |
                 H   H

Monday 11 June 2012

Electrolytes and Non-electrolytes Quiz


1. KCl is placed inside a container filled with 1 L of water.
   a. For ever 1 mol of the substance, how is the proportion of the number of particles in the container?
   b. Determine the degree of dissociation (α) of the substance!
   c. Is the solution considered a strong, weak, or non-electrolyte?

2. a. Based on the gain or the loss of oxygen, where do oxidation and reduction take place in the following reaction?
      Zn   +   PbO   ->   ZnO   +   Pb
   b. The oxidizing agent is ...
   c. The reducing agent is ...

3. a. Based on the gain or the loss of hydrogen, where do oxidation and reduction take place in the following reaction?
      H2S   +   Br2   ->   2 HBr   +    S
   b. The oxidizing agent is ...
   c. The reducing agent is ...

4. a. Based on the gain or the loss of electrons, where do oxidation and reduction take place in the following redox reactions?
      Cl2(aq)   +   2 Br-(aq)   ->   2 Cl-(aq)   +   Br2(aq)
   b. Write the ionic half equation of the oxidation!
   c. Write the ionic half equation of the reduction!

5. Write down the oxidation states of the elements in the following compounts!
   a. H3PO4
   b. ClF3
   c. MgH2
   d. CaO2
   e. NaIO3

6. a. Based on the changes in oxidation state, where do oxidation and reduction take place in the following reactions:
      2 KClO3(aq)   +   3 S(s)   ->   2 KCl(aq)   +   3 SO2(g)
   b. The oxidizing agent is ...
   c. The reducing agent it ...
   d. The oxidation result is ...
   e. The reduction result is ....


Solutions:
1. c. α = 1 so it's a strong electrolyte

2. oxidation is from Zn to ZnO, reduction is from PbO to Pb.
   oxidizing agent: PbO
   reducing agent: Zn
   tip: the one where oxidation starts from is the reducing agent

3. oxidation is from H2S to S, reduction is from Br2 2 HBr.
   oxidizing agent: Br2
   reudcing agent: H2S

4. oxidation is from 2 Br- to Br2, reduction is from Cl2 to 2 Cl-
   ionic half equation for oxidation:  2 Br- -> Br+ 2e-
   ionic half equation for reduction: Cl+ 2e-> 2 Cl-

5. a. +1 +5 -2
   b. +3 -1
   c. +2 -1
   d. +2 -1
   e. +1 +5 -2

6. oxidation is from 3 S to 3 SO2, reduction is from 2 KClO3 to 2 KCl
   oxidizing agent: KClO3
   reducting agent: S
   oxidation result: SO2
   reduction result: KCl